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Continuous flow conversion of biomass-derived methyl levulinate into gamma valerolactone using functional metal organic frameworks
(2019)
Zirconium based metal organic framework, UiO-66 (Zr), was successfully synthesized via solvothermal method, followed by various characterization including XRD, thermal analysis, N2 physisorption and TEM. As-synthesized ...
Towards the photophysical studies of humin by-products
(Royal Society of Chemistry, 2017)
Biomass conversion into chemicals, materials and fuels emerged in the past decade as the most promising alternative to the current petroleum-based industry. However, the chemocatalytic conversion of biomass and bio-derived ...
Benign-by-design preparation of iron oxides/humins catalytic nanocomposites
(Royal Society of Chemistry, 2017)
The current acid-catalyzed conversion of biomass feedstocks yields substantial quantities of undesired by-products called humins, for which applications are yet to be found. This work aims to provide a starting point for ...
Catalytic insights into the production of biomass-derived side products methyl levulinate, furfural and humins
(Elsevier, 2017)
Biomass conversion into useful chemicals, materials and fuels emerged as a promising alternative toward replacing the current production of most of these commodities and specialty products from petroleum feedstocks. ...
Biomass promises: A bumpy road to a renewable economy
(Bentham Science Publisher, 2018)
Biomass conversion strategies have been taking hold of the scientific community agenda in the evolution of renewable chemical and energy industries. Nonetheless, biomass conversion yet presents challenges due to its ...
Reconstruction of humins formation mechanism from decomposition products: A GC-MS study based on catalytic continuous flow depolymerizations
(Elsevier, 2019)
Humins, a by-product of biomass chemical conversion technologies, still present controversies in their structural and mechanistic identification. Traditional studies of the structure and mechanism have focused so far on ...
Aldol Condensation of Furfural with Acetone Over Mg/Al Mixed Oxides. Influence of Water and Synthesis Method
(MDPI, 2019)
Aldol condensation of furfural and acetone (an important initial step to obtain diesel from biomass) was studied over MgAl mixed oxides. The influence of the utilization of microwaves and/or a surfactant (Pluronic 123) ...
Mechanochemical Synthesis of Nickel-Modified Metal–Organic Frameworks for Reduction Reactions
(MDPI, 2021)
In this work, we report the incorporation of nickel oxide nanoparticles into a metal–organic framework (MOF) structure by a solvent-free mechanochemical strategy. In particular, the zirconium-based MOF UiO-66 was modified ...
Tuning the Selectivity of the Hydrogenation/Hydrogenolysis of 5-Hydroxymethylfurfural under Batch Multiphase and Continuous-Flow Conditions
(Wiley, 2022)
The hydrogenation/hydrogenolysis of 5-hydroxymethylfurfural (HMF) has been carried out either under single (aqueous) phase or batch multiphase (MP) conditions using mutually immiscible aqueous/hydrocarbon phases, 5?% Ru/C ...