Trans-ferulic acid valorization into stilbene derivatives via tandem decarboxylation/Heck coupling using Pd/Al-SBA-15 materials

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Author
Maties, G.
Gonzalez-Arellano, C.
Luque, R.
Montejano-Nares, E.
Ivars-Barceló, F.
Pineda, A.
Publisher
Elsevier
Date
2022
Subject
C–C coupling; Decarboxylation; Pd/Al-SBA-15; Stilbenes
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Abstract
Pd-containing Al-SBA-15 materials were prepared and characterized in view of their utilization in the two-step valorization of trans-ferulic acid into stilbenes via tandem decarboxylation/Mizoroki-Heck coupling. Materials were found to be highly active and selective in the proposed chemistries, with quantitative conversion to target products under mild reaction conditions (typically 100 °C, 3–6 h reaction). Relevant insights on catalyst deactivation via sintering (Pd nanoparticles agglomeration) were also observed for the synthesized materials.
URI
http://hdl.handle.net/10396/32005
Fuente
Maties, G., Gonzalez-Arellano, C., Luque, R., Montejano-Nares, E., Ivars-Barceló, F., & Pineda, A. (2022). Trans-ferulic acid valorization into stilbene derivatives via tandem decarboxylation/Heck coupling using Pd/Al-SBA-15 materials. Materials Today Chemistry, 25, 100971. https://doi.org/10.1016/j.mtchem.2022.100971
Versión del Editor
https://doi.org/10.1016/j.mtchem.2022.100971
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