Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

Balu, Alina M.; Lin, Carol S.K.; Liu, Hongli; Li, Yingwei; Vargas, Carolina; Luque, Rafael

Author

Balu, Alina M.

Lin, Carol S.K.

Liu, Hongli

Li, Yingwei

Vargas, Carolina

Luque, Rafael

Publisher

Wiley

Date

2013

Subject

Heterogeneous catalysis
Metal-organic frameworks
Microwave chemistry
Nanoparticles
Oxidation

Abstract

A highly active Fe containing MIL-101 material has been prepared by using a simple microwave-assisted deposition methodology. The material, characterized by several techniques including N2physisorption, XPS and TEM, was found to have a significantly enhanced acidity due to the incorporation of ca. 2 wt.% Fe in the form of hematite Fe2O3phase. Fe/MIL-101 exhibited excelling activities in aqueous phase oxidations of alcohols and alkenes using hydrogen peroxide as green oxidant.

Description

Supplementary data associated with this article can be found, in the online version, at http://dx.doi.org/10.1016/j.apcata. 2013.01.037.

URI

http://hdl.handle.net/10396/35530

Fuente

Alina Mariana Balu, Carol Sze Ki Lin, Hongli Liu, Yingwei Li, Carolina Vargas, Rafael Luque, Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations, Applied Catalysis A: General, Volume 455, 2013, Pages 261-266, ISSN 0926-860X, https://doi.org/10.1016/j.apcata.2013.01.037.

Versión del Editor

https://doi.org/10.1016/j.apcata.2013.01.037