Copper Tridentate Schiff Base Complex Supported on SBA-15 as Efficient Nanocatalyst for Three-Component Reactions under Solventless Conditions
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Author
Diarjani, Elham Sadat
Rajabi, Fatemeh
Yahyazadeh, Asieh
Puente-Santiago, A.R.
Luque, Rafael
Publisher
MDPIDate
2018Subject
Copper Schiff base complexSBA-15 dihydropyrimidinones
Solvent-free reaction
Biginelli reaction
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The anchorage of a supported copper Schiff base complex on SBA-15 materials provides highly efficient heterogeneous catalysts towards the solvent-free synthesis of dihydropyrimidinones derivatives via the Biginelli condensation reaction. The novel nanocatalysts exhibited a highly ordered mesostructure with a surface area of 346 m2g−1 and an average pore diameter of 8.6 nm. Additionally, the supported copper nanocatalysts were reused at least ten times, remaining almost unchanged from the initial activity. Both the mesoporous scaffold and the tridentate Schiff base ligand contributed to the stabilization of copper species.