Listar ceiA3 por autor "2721132a-1383-403c-8438-0cd49ce97b8d"
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EPR and CV studies cast further light on the origin of the enhanced hydrogen production through glycerol photoreforming on CuO:TiO2 physical mixtures
Martín-Gómez, Juan; Hidalgo-Carrillo, J.; Montes, Vicente; Estévez, R.; Escamilla, Juan Carlos; Marinas, Alberto; Urbano, Francisco José (Elsevier, 2021)Different CuO nanoparticles were synthesized and tested in CuO:TiO2 physical mixtures for hydrogen production through glycerol photoreforming. CuO alone was inactive whereas its presence in CuO:TiO2 mixtures significantly ... -
Fourth generation synthesis of solketal by glycerol acetalization with acetone: A solar-light photocatalytic approach
Hidalgo-Carrillo, J.; Estévez, R.; López Tenllado, Francisco Javier; Bautista, Felipa M.; Urbano, Francisco José; Marinas, Alberto (Elsevier, 2021)Background: Biomass is the only renewable alternative to fossil fuels to produce chemicals. In this sense, glycerol is an important biomass-derived platform chemical obtained as a by-product during biodiesel generation. ... -
Hydrogen photo-production from glycerol on platinum, gold and silver-modified TiO2-USY62 catalysts
López Tenllado, Francisco Javier; Estévez, R.; Hidalgo-Carrillo, J.; López Fernández, Silvia; Urbano, Francisco José; Marinas, Alberto (Elsevier, 2022)In this work, photocatalysts consisting of TiO2 supported on zeolite (USY62) were synthesized by sol-gel method and, subsequently, a noble metal (Pt, Au, or Ag) was incorporated by impregnation or photodeposition. Zeolite-TiO2 ... -
Hydrogen photoproduction on TiO2-CuO artificial olive leaves
Martín-Gómez, Juan; Hidalgo-Carrillo, J.; Estévez, R.; Urbano, Francisco José; Marinas, Alberto (Elsevier, 2021)Olive leaves were used as biotemplates to synthesize diverse TiO2-CuO solids. A successful replication of trichomes and internal channels was evidenced by SEM, whereas a good dispersion of Cu and Ti atoms was observed by ... -
Optimization by response surface methodology of the reaction conditions in 1,3-selective transesterification of sunflower oil, by using CaO as heterogeneous catalyst
Calero, Juan; Luna, Diego; Luna, Carlos; Bautista, Felipa M.; Romero, Antonio A.; Posadillo, Alejandro; Estévez, R. (Elsevier, 2020)In this work, the experimental conditions for the transesterification reaction of sunflower oil, over commercial calcium oxide (CaO) as heterogeneous catalysts, have been optimized employing a multi-factorial design based ... -
Sulfonated carbons from olive stones as catalysts in the microwave-assisted etherification of glycerol with tert-butyl alcohol
Estévez, R.; Aguado-Deblas, Laura; Montes, Vicente; Caballero, Álvaro; Bautista, Felipa M. (Elsevier, 2020)Sulfonated carbons have been prepared from an important waste in Andalusia, the olive stones. The sulfonic acid groups incorporation has been made by sulfuric acid treatment and different conditions have been tested, i.e., ... -
Sulfonated organosilica-aluminum phosphates as useful catalysts for acid-catalyzed reactions: Insights into the effect of synthesis parameters on the final catalyst
Aguado-Deblas, Laura; Estévez, R.; López Tenllado, Francisco Javier; Luna, Diego; Bautista, Felipa M. (Elsevier, 2022)The synthesis, by a sol-gel method, of organosilica-aluminum phosphates, (X)-AlPO(Y)-(Z), using three different silica precursors (X) 2-(4-chlorosulfonylphenyl)ethyltrimethoxysilane (C), 3-(mercaptopropyl)trimethoxysilane ...