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Towards industrial furfural conversion: selectivity and stability of palladium and platinum catalysts under continuous flow regime
(2019)
Furfural is an important biorefinery platform chemical, derived from hemicelluloses which represent an import fraction of lignocellulosic biomass feedstocks and waste streams originating from them. Recently, promising ...
Valorisation of humins-extracted 5-Methoxymethylfurfural: towards high added value furanics via continuous flow catatalytic hydrogenation
(ACS Publications, 2019)
The formation of humins is one drawback of biomass valorization (e.g. hemicellulosic fraction) towards platform chemicals and fuels. Furanic compounds including 5-hydroxymethylfurfural and 5-methoxymethylfurfural can be ...
Continuous flow synthesis of menthol via tandem cyclisation–hydrogenation of citronellal catalysed by scrap catalytic converters
(Royal Society of Chemistry, 2019)
A continuous flow synthesis of menthol starting from citronellal catalysed by scrap catalytic converters is reported. The reaction was conducted in a tandem system connecting in series two catalytic systems, with the first ...
Reconstruction of humins formation mechanism from decomposition products: A GC-MS study based on catalytic continuous flow depolymerizations
(Elsevier, 2019)
Humins, a by-product of biomass chemical conversion technologies, still present controversies in their structural and mechanistic identification. Traditional studies of the structure and mechanism have focused so far on ...
Mechanochemical Preparation of Novel Polysaccharide-Supported Nb2O5 Catalysts
(MDPI, 2019)
Polysaccharides extracted from natural sources can be used as starting material for the preparation of nanoparticle supported composites. A novel family of bio-nanocomposites was mechanochemically synthesized by using ...
Fe-Containing MOFs as Seeds for the Preparation of Highly Active Fe/Al-SBA-15 Catalysts in the N-Alkylation of Aniline
(MDPI, 2019)
We have successfully incorporated iron species into mesoporous aluminosilicates (AlSBA15) using a simple mechanochemical milling method. The catalysts were characterized by nitrogen physisorption, inductively coupled plasma ...
NH4F Modified Al-SBA-15 Materials for Esterification of Valeric Acid to Alkyl Valerates
(MDPI, 2019)
Al-SBA-15 materials were functionalized by ball milling with several niobium loadings (0.25–1 wt.%) and/or with several F- loadings, using NH4F as a precursor. The catalysts synthesized in this study were characterised by ...
Mechanochemically Synthesized Supported Magnetic Fe-Nanoparticles as Catalysts for Efficient Vanillin Production
(MDPI, 2019)
Magnetically separable nanocatalysts were synthesized by incorporating iron nanoparticles on a mesoporous aluminosilicate (Al-SBA-15) through a mechanochemical grinding pathway in a single step. Noticeably, magnetic features ...
Continuous-Flow Hydrogenation of Methyl Levulinate Promoted by Zr-Based Mesoporous Materials
(MDPI, 2019)
Several Zr-based materials, including ZrO2 and Zr-SBA-15, with different silicon/zirconium molar ratios, and ZrO2/Si-SBA-15 (where SBA-15 stands for Santa Barbara Amorphous material no. 15), have been prepared as hydrogenation ...