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dc.contributor.authorVaccaro, Luigi
dc.contributor.authorFerlin, Francesco
dc.contributor.authorGiannoni, Tommaso
dc.contributor.authorZuliani, Alessio
dc.contributor.authorPiermatti, Oriana
dc.contributor.authorLuque, Rafael
dc.date.accessioned2019-01-24T12:33:29Z
dc.date.available2019-01-24T12:33:29Z
dc.date.issued2019
dc.identifier.urihttp://hdl.handle.net/10396/17705
dc.descriptiones_ES
dc.description.abstractGold‐incorporated SBA‐15 catalyst was prepared by a solvent‐free ball milling approach. The catalyst showed high reactivity and selectivity in the reduction of a variety of nitroarenes to anilines operating in absolute EtOH using NaBH4 as reducing agent. The catalyst was reused in batch conditions over 5 consecutive runs without detecting any losses of activity and selectivity. Considering the high chemical stability and reusability of the catalytic system, a continuous flow protocol was also investigated and defined in order to minimize the production of waste associated to the process and optimize the continuous reuse of the catalyst. Benefits of flow conditions were proven by TON values that increased from 47.5 to 1902 and also by the minimization of both leaching (9.5 vs 1 ppm) and E‐factor values (8 vs 23 in batch).es_ES
dc.format.mimetypeapplication/pdfes_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0/es_ES
dc.sourceChemSusChem 12, 1-8 (2019)es_ES
dc.subjectHeterogeneous catalysises_ES
dc.subjectSBA-15es_ES
dc.subjectReduction of nitroareneses_ES
dc.subjectGold NPes_ES
dc.subjectFlow conditiones_ES
dc.titleSustainable protocol for the reduction of nitroarenes by heterogeneous Au@SBA‐15 using NaBH4 under flow conditionses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://dx.doi.org/10.1002/cssc.201802359es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/721290es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES


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