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dc.contributor.authorCerdana, Kenneth
dc.contributor.authorOuyang, Weiyi
dc.contributor.authorColmenares, Juan C.
dc.contributor.authorMuñoz-Batista, Mario J.
dc.contributor.authorLuque, Rafael
dc.contributor.authorBalu, Alina M.
dc.date.accessioned2019-03-19T10:17:28Z
dc.date.available2019-03-19T10:17:28Z
dc.date.issued2019
dc.identifier.urihttp://hdl.handle.net/10396/18220
dc.description.abstractGraphitic carbon nitride enriched with ZnO or Fe2O3 were synthesized using a simple one-pot mechanochemical method. By using this method, composite samples were synthetized without the production of any potentially hazardous waste. The synthesized materials were used as catalysts during the selective photo-oxidation of benzyl alcohol. Both composite materials displayed an enhancement of the activity and benzaldehyde selectivity with respect to the pure g-C3N4. The most active catalyst was Fe2O3/g-C3N4. The conversion and benzaldehyde selectivity of this sample were 20 and 70 %, respectively. It showed a considerable increase of the benzaldehyde selectivity compared to the pure g-C3N4 and TiO2 P25 commercial reference. A complete structural and electronic characterization using Scanning Electron Microscopy-Energy Dispersive (SEM-EDX), BET measurements, X-ray diffraction (XRD), X-ray Photoelectron (XPS), and UV–visible spectroscopies was carried out. The characterization analysis pointed out the leading role of the crystallinity and surface concentration over the activity and benzaldehyde selectivity of the reactiones_ES
dc.format.mimetypeapplication/pdfes_ES
dc.language.isoenges_ES
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0/es_ES
dc.subjectPhoto-catalysises_ES
dc.subjectGraphitic carbon nitridees_ES
dc.subjectBenzyl alcoholes_ES
dc.subjectZnOes_ES
dc.subjectFe2O3es_ES
dc.titleFacile mechanochemical modification of g-C3N4 for selective photo-oxidation of benzyl alcoholes_ES
dc.typeinfo:eu-repo/semantics/preprintes_ES
dc.relation.publisherversionhttps://doi.org/10.1016/j.ces.2018.04.001es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/MSCA-ITN-2014-641861es_ES
dc.relation.projectIDGobierno de España. FJCI-2016-29014es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES


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