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Effects of Fe3+ substitution on Zn-Al layered double hydroxides for enhanced NO photochemical abatement
dc.contributor.author | Pastor, Adrián | |
dc.contributor.author | Rodríguez-Rivasa, Fredy | |
dc.contributor.author | Cruz-Yusta, M. | |
dc.contributor.author | Martín, Francisco | |
dc.contributor.author | Pavlovic, I. | |
dc.contributor.author | Sánchez Granados, Luis | |
dc.contributor.author | Miguel, Gustavo de | es_ES |
dc.date.accessioned | 2020-01-14T08:15:43Z | |
dc.date.available | 2020-01-14T08:15:43Z | |
dc.date.issued | 2020 | |
dc.identifier.uri | http://hdl.handle.net/10396/19276 | |
dc.description.abstract | In this work the ability of ZnAlFe-CO3 layered double hydroxides (LDHs) as highly efficient UV-Vis light photocatalysts for the photochemical oxidation of NO gas was studied. LDHs with 3.5 to 4.1 M2+/M3+ and 0.33 to 1.55 Fe/Al ratios were prepared by a coprecipitation method. The samples were characterized by different techniques such as XRD, XPS, FT-IR, ICP-MS, TG, SBET, SEM and Diffuse reflectance (DR). The increased presence of the Fe3+ ions gave rise to changes in the structure, morphology and optical properties of the LDHs. The prepared ZnAlFe-CO3 systems exhibited increased surface area and enhanced visible-light absorbance. The photochemical NO abatement resulted in outstanding conversion efficiency (56 %) and selectivity (93 %) for the iron containing samples, due to a decrease of the e-/h+ recombination, higher generation of ⋅O2- and ⋅OH radicals and their NO2 adsorption ability. | es_ES |
dc.format.mimetype | application/pdf | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.rights | https://creativecommons.org/licenses/by-nc-nd/4.0/ | es_ES |
dc.source | Chemical Engineering Journal (2020) | es_ES |
dc.subject | LDH | es_ES |
dc.subject | Hydrotalcite | es_ES |
dc.subject | Photocatalyst | es_ES |
dc.subject | Nitrogen oxides | es_ES |
dc.title | Effects of Fe3+ substitution on Zn-Al layered double hydroxides for enhanced NO photochemical abatement | es_ES |
dc.type | info:eu-repo/semantics/preprint | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.cej.2020.124110 | es_ES |
dc.relation.projectID | Gobierno de España. MAT2017-88284-P | es_ES |
dc.relation.projectID | Gobierno de España. CTQ2017-84221-R | es_ES |
dc.relation.projectID | Gobierno de España. FPU16/05041 | es_ES |
dc.relation.projectID | Junta de Andalucía. FQM-214 | es_ES |
dc.relation.projectID | Junta de Andalucía. FQM-175 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |