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dc.contributor.authorCova, Camilla María
dc.contributor.authorZuliani, Alessio
dc.contributor.authorManno, Roberta
dc.contributor.authorSebastian, Victor
dc.contributor.authorLuque, Rafael
dc.date.accessioned2020-01-28T11:02:48Z
dc.date.available2020-01-28T11:02:48Z
dc.date.issued2020
dc.identifier.urihttp://hdl.handle.net/10396/19399
dc.description.abstractThe catalytic activity of the scrap ceramic-core of automotive catalytic converters (SCATs) was investigated in the continuous-flow hydrogenation of different biomass derived chemicals. The waste SCATs powders were deeply characterized by ICP-MS, TGA, MP-AES, XRD, N2 physisorption, HRTEM and EDS before and after the utilization as catalyst. The hydrogenation reactions of isopulegol to menthol; cinnamyl alcohol to hydrocinnamyl alcohol; isoeugenol to dihydroeugenol; vanillin to vanillyl alcohol and benzaldehyde to benzyl alcohol were performed studying the influence on of various reaction parameters (temperature, pressure, flow rate and concentration of the starting material) on final yields. The outstanding performance and stability obtained for the low metal content of waste-derived catalysts can be attributed to the co-presence of different noble metals as well as to the composite structure itself.es_ES
dc.format.mimetypeapplication/pdfes_ES
dc.language.isoenges_ES
dc.publisherRSCes_ES
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0/es_ES
dc.sourceGreen Chemistry (2020)es_ES
dc.subjectContinuous-flowes_ES
dc.subjectMentholes_ES
dc.subjectCatalytic converterses_ES
dc.subjectWastees_ES
dc.subjectHydrogenationses_ES
dc.titleScrap waste automotive converters as efficient catalysts for the continuous-flow hydrogenations of biomass derived chemicalses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C9GC04091Aes_ES
dc.relation.projectIDMINECO/CTQ2016-78289-Pes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/721290es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/embargoedAccesses_ES


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