SBA-Pr-Is-TAP Functionalized Nanostructured Silica as a Highly Selective Fluorescent Chemosensor for Fe3+ and Cr2O72− Ions in Aqueous Media

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Author
Ziarani, Ghodsi Mohammadi
Akhgar, Maryam
Mohajer, Fatemeh
Badiei, Alireza
Luque, Rafael
Publisher
MDPIDate
2021Subject
SBA-Pr-Is-TAPFunctionalized mesoporous silica
Chemosensor
Fluorescent spectroscopy
Aqueous media
Fe3+ and Cr2O72− ions
2,4,6-triaminoprymidine
Isatin
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SBA-Pr-Is-TAP was synthesized via functionalization of SBA-15. The synthesized hybrid nanomaterial was characterized by various techniques including FT-IR, TGA, XRD, SEM, and BET. SBA-Pr-Is-TAP could precisely bind Fe3+ and Cr2O72− ions among a range of different species in aqueous media, consequently acting as a nanoporous chemosensor of Fe3+ and Cr2O72− ions. An excellent linear relation was observed between the nanoporous chemosensor and ion concentrations, with acceptable detection limits of 2.43 × 10−6 M and 3.96 × 10−7 M for Fe3+ and Cr2O72− ions respectively.