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dc.contributor.authorAmaro-Gahete, J.
dc.contributor.authorKaczmarek, Anna M.
dc.contributor.authorEsquivel, Dolores
dc.contributor.authorJiménez-Sanchidrián, César
dc.contributor.authorVan der Voort, Pascal
dc.contributor.authorRomero-Salguero, F.J.
dc.date.accessioned2023-01-11T08:52:13Z
dc.date.available2023-01-11T08:52:13Z
dc.date.issued2019
dc.identifier.urihttp://hdl.handle.net/10396/24488
dc.description.abstractGraphene-based materials exhibit outstanding physical properties and so are potentially applicable in a great variety of fields. Unlike their corresponding oxides, graphite and graphene are not prone to functionalization. Diels-Alder reactions are among the scarce reactions that they can undergo without disrupting their conjugated sp2 systems. Herein, the reaction between graphite and 3,6-di(2-pyridyl)-1,2,4,5-tetrazine under different conditions affords several graphene-based materials consisting of dipyridylpyridazine functionalized few layer graphene, multilayer graphene and graphite whose sheets act as ligands for the grafting of a europium complex. These three materials show strong red emission under 365 nm UV radiation. Their emitting particles can be visualized by confocal microscopy. The rich coordination chemistry of dipyridylpyridazine ligands envisages novel properties for similarly functionalized graphene-based materials grafted with other metal complexes.es_ES
dc.format.mimetypeapplication/pdfes_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0/es_ES
dc.sourceChemistry – A European Journal 25, 6823-6830 (2019)es_ES
dc.subjectGraphen noanosheetses_ES
dc.subjectEuropiumes_ES
dc.subjectDipyridylpyridazinees_ES
dc.subjectDiels-Alderes_ES
dc.titleLuminescent graphene-based materials via europium complexation on dipyridylpyridazine-functionalized graphene sheetses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201900512es_ES
dc.relation.projectIDGobierno de España. FPU17/03981es_ES
dc.relation.projectIDJunta de Andalucía. FQM-346es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES


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